| Lecture 1 |
Vision Statement, Administrative Details. Introduction. Taxonomy of chemical species. Origins of modern chemistry. Reading : Ch. 1. |
| Lecture 2 |
Classification schemes for the elements. Mendeleyev and the Periodic Table. Atomic structure. Reading : Ch. 1, Ch. 2, Appendix A, Elemental Bibliography . |
| Lecture 3 |
Rutherford model of the atom, Bohr model of hydrogen. Reading : Ch. 3.1, 3.5-3.8 (text); LN 1, pp. 2-5 (archives). |
| Lecture 4 |
Atomic spectra of hydrogen, matter/energy interactions involving atomic hydrogen. Reading : Ch. 3.3, 3.4, 3.9, 3.10 (text); LN 1, pp. 5-16 ( archives ), Cecilia Payne. |
| Lecture 5 |
The Shell Model (Bohr- Sommerfeld Model) and multi-electron atoms. Quantum numbers: n, l, m, s. Reading: Ch. 3.2, 3.10-3.12, 3.15-3.18 (text); LN 1 (archives ). |
| Lecture 6 |
De Broglie , Heisenberg, and Schrödinger. The Aufbau Principle, Pauli Exclusion Principle, and Hund's Rules. Photoelectron Spectroscopy. Average Valence Electron Energy. Reading : Ch. 3.24, 3.25, 5.1-5.7, 5.10 (text); LN 2 ( archives ). |
| Lecture 7 |
Octet stability by electron transfer: ionic bonding. Properties of ionic compounds: crystal lattice energy. Reading : Ch. 5.1-5.7, 5.10 (text); LN 2, pp. 1-12 (archives). |
| Lecture 8 |
Born- Haber cycle. Octet stability by electron sharing: covalent bonding. Lewis structures. Hybridization. Reading : Ch. 4.1-4.7, 4.10-4.12, 4.17 (text). |
| Lecture 9 |
Electronegativity , partial charge, polar bonds and polar molecules. Ionic character of covalent bonds, Pauling's calculation of heteronuclear bond energies. Reading : Ch. 5.7, 5.10, 4A.1, 4A.3 (text). |
| Lecture 10 |
LCAO MO, Energy Level Diagrams for H 2 , He 2 , Li 2 . Hybridization, double bonds and triple bonds, paramagnetism and diamagetism . Reading : Ch. 4A.1-4A.4, 14-4-14.6, 8.2, 8.9 (text); LN 2, pp.12- end (archives). |
| Lecture 11 |
The Shapes of Molecules, Electron Domain Theory, Secondary Bonding. Reading : Ch. 4.14, 4.15 (text). |
| Lecture 12 |
Metallic Bonding, Band Theory of Solids ( Heitler and London ), Band Gaps in Metals, Semiconductors, and Insulators, Absorption Edge of a Semiconductor. Reading : Ch. 5.9-5.11, 9.4 (text); M.12 (modules); LN 2, pp. 25-26, LN 3 ( archives ). |
| Lecture 13 |
Intrinsic and Extrinsic Semiconductors, Doping, Compound Semiconductors, Molten Semiconductors. Reading : M.12 (modules); LN 3 ( archives ). |
| Lecture 14 |
Introduction to the Solid State , the 7 Crystal Systems, the 14 Bravais Lattices. Reading : 9.6-9.12 (text), M.1-M.4, M.8 (modules); pp. 3-11 (supplement); LN 4 ( archives ). |
| Lecture 15 |
Properties of Cubic Crystals : simple cubic, face-centered cubic, body-centered cubic, diamond cubic. Crystal coordinate systems, Miller indices. Reading : 9.6-9.12 (text); M.1-M.6 (modules); pp. 3-23; 150-155; 167-174 (supplement); LN 4 (archives). |
| Lecture 16 |
Characterization of atomic structure: the generation of x-rays and Moseley's Law. Reading : pp. 139-141; 144-149; 175-181 (supplement); LN 5, pp. 1-9 ( archives ). |
| Lecture 17 |
X-ray spectra, Bragg's Law. Reading : pp. 26-31; 186-191 (supplement); LN 5 (archives). |
| Lecture 18 |
X-ray diffraction of crystals: diffractometry , Debye-Scherrer , Laue . Crystal symmetry. Reading : pp. 26-31 (supplement); LN 5 ( archives ). |
| Lecture 19 |
Defects in crystals: point defects, line defects, interfacial defects, voids. Reading : M.11 (modules); pp. 39-43, 47-53 (supplement); LN 6 ( archives ). |
| Lecture 20 |
Amorphous solids, glass formation, inorganic glasses: silicates. Reading : 9.1, 9.2 (text); M.15 (modules); pp. 31-32 (supplement); LN 7, pp. 1-3, 5-9 ( archives ). |
| Lecture 21 |
Engineered glasses: network formers, network modifiers, intermediates. Properties of silicate glasses. Metallic glass. Reading : 9.1, 9.2 (text); M.15 (modules); pp. 31-32 (supplement); LN 7, pp. 1-3, 5-9 ( archives ). |
| Lecture 22 |
Chemical kinetics: the rate equation, order of reaction, rate laws for zeroth , first, and second order reactions. Temperature dependence of rate of reaction. Reading :10.1 -10.4, 14.1-14.8, 14.10, 14.11 (text); LN 8 ( archives ). |
| Lecture 23 |
Diffusion: Fick's First Law and steady-state diffusion, dependence of the diffusion coefficient on temperature and on atomic arrangement. Reading : pp. 63-68; 85-95 (supplement); LN 9, pp. 1-6 ( archives ). |
| Lecture 24 |
Fick's Second Law ( FSL ) and transient-state diffusion; error function solutions to FSL . Reading : pp. 68-78, 95-101 (supplement); LN 9, all (archives). |
| Lecture 25 |
Solutions: solute, solvent, solution, solubility rules, solubility product. Reading : 8.10-8.13, 8.15 (text); SOL.1-SOL.10 (modules). |
| Lecture 26 |
Acids and Bases: Arrhenius , Brønsted -Lowry, and Lewis definitions, acid strength and pH. Reading : Ch. 11 (text). |
| Lecture 27 |
Organic chemistry: basic concepts, alkanes , alkenes, alkynes, aromatics, functional groups, alcohols and ethers, aldehydes and ketones , esters, amines. Reading : O1.1-O1.7, O1.10-O1.11, O1.13, O1.14, O2.1, O2.3, O2.4 (modules). |
| Lecture 28 |
Polymers: synthesis by addition polymerization and by condensation polymerization. Reading : P.1-P.3, P.7-P.9 (modules). |
| Lecture 29 |
Structure-property relationships in polymers, crystalline polymers. Reading : P.1-P.3, P.7-P.9 |
| Lecture 30 |
Biochemistry: the amino acids, peptides, and proteins. Reading : BIO.1 - BIO.3; BIO.5 |
| Lecture 31 |
Protein structure: primary, secondary, tertiary; denaturing of proteins. Reading : BIO.6, BIO.9. |
| Lecture 32 |
Lipids: self assembly into bilayers . Nucleic acids, DNA, encoding information for protein synthesis. Electrochemistry of batteries and fuel cells. Reading : BIO.6, BIO.9. |
| Lecture 33 |
Phase diagrams - basic definitions: phase, component, equilibrium; one-component phase diagrams. Reading : pp. 103-113 (16.1 - 16.3) (supplement); LN 10 Part A 1-3 (archives). |
| Lecture 34 |
Two-component phase diagrams: complete solid solubility. Reading : pp. 103-113 (16.1 - 16.3) (supplement); Part B 1-9 (archives). |
| Lecture 35 |
Two-component phase diagrams: limited solid solubility. Lever Rule. Reading : pp. 113-119 (16.4) (supplement); LN 10 Part B 1-9 (archives). |
| Lecture 36 |
Wrap-up: closing remarks about 3.091. Student Course Evaluations.
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